Effect of ligand substituents on supramolecular self-assembly and electrochemical properties of copper(II) complexes with benzoylhydrazones: X-ray crystal structures and cyclic voltammetry

Abstract

Complexation of copper(II) with a series of hetero-donor chelating Schiff bases (HLLR) of para-substituted benzhydrazides (with R=OH, NO2, CH3O, Cl and tert-butyl substituents) and acetone affords mononuclear [Cu(LLR)2] molecules: 1 [Cu(anbhz)2] (R=NO2); 2 [Cu(ahbhz)2] (R=OH) 3 [Cu(ambhz)2] (R=CH3O); 4 [Cu(acbhz)2] (R=Cl); and 5 [Cu(atbhz)2] (R=tert-butyl). Single-crystal X-ray diffraction results for 2–5 reveal their various supramolecular architectures including 1D and 2D dimensionalities. A detailed analysis of crystal structures allows to gain insight into intermolecular interactions accountable for self-assembly into different networks as well as for various physicochemical properties of the compounds. The major interactions include O–H⋯N hydrogen bonds (2) as well as CH⋯N and axial Cu⋯O (3); π⋯π stacking (4) and van der Waals CH⋯C interactions (5). All compounds are characterized by elemental analyses; IR and UV–Vis spectroscopy as well as magnetic susceptibility and cyclic voltammetry measurements. Electrochemical studies reveal the dependence of [Cu(LLR)2]/[Cu(LLR)2]− reduction potentials on substituents of benzoylhydrazonoate ligands.