Abstract

In this study, 304 SS/Al2O3 ceramic structural parts were successfully prepared by laser heat source biasing using AgCuTi as filler. The method removes residual thermal stresses by retaining unfused 304 SS (stainless steels), provides protection to the Al2O3 ceramics, and connects the two sides of the substrate using the wettability of the AgCuTi filler. Based on the 304 SS/Al2O3 connectivity, the Gibbs free energy changes of Ti–Fe and Ti–Cu compounds at the weld were calculated from the thermodynamics perspective to determine the possible phases. The temperature field of the joint was also investigated using finite element simulation to analyze the temperature changes in the fusion zone, the interface I (304 SS/AgCuTi), and the interface II (AgCuTi/Al2O3) under different welding parameters, and predict the welding parameters that can achieve an effective connection without destroying the Al2O3 ceramics, which were experimentally verified. The maximum tensile strength of the joints was 94.9 MPa when the laser power was increased from 372 W to 432 W. The maximum tensile strength of the joints was 90.5 MPa when the laser speed was increased from 440 mm/min to 630 mm/min. The maximum tensile strength of the joints was 89 MPa when the laser offset was increased from 1.4 mm to 1.9 mm. By analyzing the microstructure, it was found that brittle intermetallic compounds (IMCs) such as FeTi and Cu2Ti were generated at interface I, which was the main factor affecting the strength of the joint. Many Ag(s,s) and Cu(s,s) solid solutions were found at AgCuTi and interface II. By analyzing the microstructure, the interface organization of the joint is composed of 304 SS + α-Fe/γ-Fe + FeTi/Cu2Ti + Ag(s,s)/Cu(s,s) + Ti2Cu + Al2O3. Finally, the Arrhenius function calculates the diffusion coefficients and diffusion concentrations of Ti and Fe elements.

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