Effect of Laser Parameters on Laser-Induced Graphene Filter Fabrication and Its Performance for Desalination and Water Purification.

Abstract

Laser-induced graphene (LIG) is a low-cost, chemical-free single-step fabrication process and has shown its potential in water treatment, electronics, and sensing. LIG fabrication optimization is mostly explored for dense polyimide (PI) polymers. However, LIG-based filters and membranes for water treatment need to be porous, and additional steps are required to get porous surfaces from PI-based surfaces. Polyethersulfone (PES) porous membranes are cost-effective and are common in water purification as compared to PI; further, the optimization of LIG fabrication on PES-based porous membranes is not explored. So, this study demonstrated the fabrication, optimization, and characterization of LIG with different laser parameters such as power, speed, image density (ID), focusing, laser platforms, and membrane support layer effect on porous PES commercial (UP010) and lab-casted 15% PES (PES15) membranes. The performance of optimized LIG filters was tested for interfacial evaporation (IE)-based desalination in single and stacked layer configuration and water purification applications such as dye removal and disinfection. IE was done in Joule heating (JH) and solar heating (SH) modes, and the UP010-ID7 LIG filter showed the highest JH evaporation rates of ∼1.1, 1.8, and 2.82 kg m-2 h-1 in single, double, and triple stacked configurations, respectively. Using a JH IE setup, the best-performing UP010-ID7 LIG filters have also shown ∼100% removal of methylene blue dye from the contaminated water. Furthermore, all LIG filters showed a complete 6-log bacterial inhibition at the 5 V filtration experiments; at 2.5 V, the optimized LIG filters showed a higher removal than the non-optimized filters. Additionally, the LIGs obtained with the aluminum platform were the best quality. This work demonstrates that laser power, ID, platform, and membrane support are critical parameters for the best-performing PES-LIG filters, and they can be effectively utilized to fabricate PES-based LIG porous surfaces for various energy, environmental, and catalysis applications.