Abstract
Laser irradiation can be employed as an auxiliary energy field to optimize functional plasma electrolytic oxidation (PEO) coatings. Herein, the mechanism of the effect of laser-assisted irradiation on the morphology and composition of ceramic coatings prepared by PEO of titanium alloys in electrolytes with sodium tetraborate-based is discussed from the perspective of plasma arc spot evolution and photoelectric synergistic effect. X-ray diffraction (XRD), transmission electron microscopy (TEM), Mott-Schottky (M-S), scanning electron microscopy (SEM), and atomic force microscopy (AFM) were used to analyze the coating characteristics. The results showed that laser-assisted irradiation promoted the oxidation of the coatings, accelerated the conversion of the anatase phase to the rutile phase, reduced the oxygen vacancy defects and formed the "ant nest" porous microstructure. Monitoring of the voltage, electric field, and plasma discharge arc spot indicated that laser-assisted irradiation restricted the electric field diffusion on the anode surface, reduced the termination voltage, and significantly increased the intensity (maximum discharge percentage increased from 14.238 % to 20.358 %) and uniformity of distribution of the plasma discharge. Instantaneous photoresponse curves and electrochemical impedance spectroscopy confirmed that the PEO coatings exhibited fast and sustained photoelectric response under simultaneous laser irradiation, progressively enhanced with increasing laser irradiation energy. The photogenerated electrons excited by the semiconductor TiO2 coating under the simultaneous irradiation of laser can be used as the initial carriers of the electron avalanche, which induces the generation of a plasma on the surface of the anode and thus enhances the plasma discharge behavior, which is the fundamental reason for the optimization of the coating characteristics.
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