Abstract

Nanocrystalline TiO 2 materials produced by an acid-catalyzed sol–gel method are used as catalysts in the photocatalytic degradation of phenol under ultraviolet light. Materials with different crystalline and morphological properties are obtained by controlling the temperature used in the calcination step. Induced light conversion and adsorption have opposite dependencies on the light intensity. The operational parameters (nature of TiO 2 crystal phase, catalyst concentration, pH and initial phenol concentration) have the expected influence in the efficiency of the photocatalytic degradation process. The effect of two different co-oxidants (H 2O 2 and Na 2S 2O 8) in the photocatalytic process is also described. A modified Langmuir–Hinshelwood kinetic model is used considering a pseudo-steady state approach in order to explain the dependence of both, the kinetic rate and adsorption equilibrium constants, on light intensity. Hydroquinone and catechol are the main intermediates of the photocatalytic reaction, as result from the reaction of phenol with photogenerated hydroxyl radicals. A possible degradation pathway is advanced.

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