Effect of ion exchange on strength and slow crack growth of a dental porcelain

Abstract

Objectives To determine the effect of ion exchange on slow crack growth (SCG) parameters ( n, stress corrosion susceptibility coefficient, and σ f0, scaling parameter) and Weibull parameters ( m, Weibull modulus, and σ 0, characteristic strength) of a dental porcelain. Methods 160 porcelain discs were fabricated according to manufacturer's instructions, polished through 1 μm and divided into two groups: GC (control) and GI (submitted to an ion exchange procedure using a KNO 3 paste at 470 °C for 15 min). SCG parameters were determined by biaxial flexural strength test in artificial saliva at 37 °C using five constant stress rates ( n = 10). 20 specimens of each group were tested at 1 MPa/s to determine Weibull parameters. The SPT diagram was constructed using the least-squares fit of the strength data versus probability of failure. Results Mean values of m and σ 0 (95% confidence interval), n and σ f0 (standard deviation) were, respectively: 13.8 (10.1 − 18.8) and 60.4 (58.5 − 62.2), 24.1 (2.5) and 58.1 (0.01) for GC and 7.4 (5.3 − 10.0) and 136.8 (129.1 − 144.7), 36.7 (7.3) and 127.9 (0.01) for GI. Fracture stresses (MPa) calculated using the SPT diagram for lifetimes of 1 day, 1 year and 10 years (at a 5% failure probability) were, respectively, 31.8, 24.9 and 22.7 for GC and 71.2, 60.6 and 56.9 for GI. Significance For the porcelain tested, the ion exchange process improved strength and resistance to SCG, however, the material's reliability decreased. The predicted fracture stress at 5% failure probability for a lifetime of 10 years was also higher for the ion treated group.