Abstract

The purpose of this study was to evaluate the effects of interpenetrating polymer network (IPN) thermoplastic resin on the flexural strength of fibre-reinforced composite (FRC) with different IPN polymer compositions. The penetration of bonding resin into semi-IPN FRC posts was also evaluated. The IPN thermoplastic resin used was UDMA-MMA monomer with either PMMA (0.5%, 2%, 5%) or PMMA-copolymer (0.5%, 2%). A no added IPN polymer resin was also made. Mixed resin was impregnated to S- and E-glass fibre rovings. These resins and resin impregnated fibres were used for flexural strength (FS) test. To evaluate the penetration of bonding resin into semi-IPN post, SEM observation was done with various impregnation time and polymerization mehods (hand-light- and oven-cure). The result of FS was recorded from 111.7 MPa (no-IPN polymer/no-fibre-reinforcement) to 543.0 MPa (5% PMMA/S-glass FRC). ANOVA showed that there were significant differences between fibre-reinforcement and no-fibre-reinforcement (p < 0.01) both in S- and E-glass fibre groups, and between 0.5% PMMA and 5% PMMA in the S-glass FRC group. SEM micrographs showed that the penetration layers of bonding resin into hand-light cured semi-IPN posts were different according to impregnation time. Fibre reinforcement is effective to improve flexural strength. The depth of penetration layer of bonding resin into semi-IPN matrix resin was improved when a hand-light cure was used.

Highlights

  • Fibre-reinforced composite (FRC) is a composite material which consists of reinforcing fibres embedded in a resin polymer matrix

  • The maximum flexural strength value of FS was recorded in 5% PMMA/S-glass fibre-reinforced composite (FRC) (543.0 MPa), and the minimum value (111.7 MPa) was observed in no-interpenetrating polymer network (IPN) polymer/no-fibre reinforcement samples

  • 24 h (a) hand light cu re (b) oven cu re. This experimental study demonstrated the effects of various interpenetrating polymer network (IPN) matrices on the flexural properties of fibre-reinforced composite (FRC)

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Summary

Introduction

Fibre-reinforced composite (FRC) is a composite material which consists of reinforcing fibres embedded in a resin polymer matrix. The resin matrix used in FRCs is typically composed of a highly cross-linked polymer such as bis-phenol A diglycidyl ether dimethacrylate (Bis-GMA), triethylene glycol dimethacrylate (TEGDMA), or urethane-dimethacrylate (UDMA) [7]. Another concept, that of interpenetrating polymer networks (IPNs), has been introduced. This is a polymer comprised of two or more kinds of polymer in network form, with continuous mutual interlacing [8] This IPN polymer has been applied to, for example, FRC root canal posts and FRC frameworks of FPD [9]. Semi-IPN for dental polymer matrices is composed of polymethylmethacrylate (PMMA) and bis-GMA, and achieves a chemical bonding between the FRC materials and luting cements or veneering composite [10]

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