Abstract
Effect of induced self-organization and liquid-crystal ordering of disordered globules of flexible amphiphilic macromolecules was observed in 1:1 mixtures of flexible and stiff helical macromolecules of similar composition. Mixtures of fully flexible macromolecules and helical macromolecules with various stiffness of backbone were studied by means of molecular dynamics simulation. It was found that if the local helical structure of the backbone is stiff enough to induce formation of aggregates with helical packing of backbone in poor solvent, the helical and flexible macromolecules segregate upon worsening of solvent quality. In dilute solution the flexible macromolecules are compacted into single globules with hydrophobic core and hydrophilic shell. The macromolecules with stiff local helical structure form aggregates of few helical chains. The aggregates have a core composed by intertwined backbones which is surrounded by a hydrophilic outer shell consisting of side groups. Increase of volume fraction o...
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
