Effect of hydrolyzed polyacrylamide used in polymer flooding on droplet–interface electro-coalescence: Variation of critical electric field strength of partial coalescence

Abstract

Polymer flooding is widely used in petroleum industry to enhance oil recovery. However, presence of polymer molecules in produced liquids can influence the droplet coalescence at oil–water interface in electric dehydration separators. In this study, the influence of hydrolyzed polyacrylamide (HPAM) on droplet–interface coalescence was examined through high-speed recording and observation. Deformation of droplets of aqueous polymer solution under electric fields was experimentally observed. The images showed droplets collapsed to filament without pinch-off due to viscoelasticity. Meanwhile, fine secondary droplets erupted from the summit of filament, which was detrimental to dehydration efficiency. A critical electric field strength (Ecrit) beyond which partial coalescence occurred was identified. The effects of the initial droplet size, HPAM concentration, electric field waveform and frequency were explored. The results showed that Ecrit increased with the decrease in initial droplet radius or the increase in HPAM concentration. Four kinds of AC or pulsatile electric fields (PEFs) were used including sinusoidal AC (sine AC), square, pulsed DC (PUDC) and pulsed AC (PUAC) waveforms. The increase in frequency suppressed the electro-induced stretching of droplets in the vertical direction, inhibiting partial coalescence. For these different electric fields, the increase in Ecrit with elevated frequencies followed different ways. Overall, Ecrit of square waveform was larger than those of other waveforms; however, Ecrit of PUAC and sine AC waveforms may exceed that of square waveform at high frequencies. These findings are useful for the development of electro-dehydration separators for oils containing dissolved polymers in the dispersed aqueous phase.