Abstract

The low volumetric efficiency of the diaphragm compressor under hydrogen refueling process, which hereby results in poor energy efficiency and high cost of hydrogen applications, should be paid attention to. This paper presents theoretical analysis and experimental investigation of the factors affecting the volumetric efficiency of the diaphragm compressor for hydrogen refueling process, focusing on the influence of hydraulic oil compressibility. A mathematical model was established to estimate the volumetric efficiency of diaphragm compressors, in which the effects of clearance volume, superheating of suction gas and pressure loss were taken into account and the emphasis was focused on the compressibility of hydraulic oil. A test rig was built to validate the theoretical model and further experimental investigations were carried out to identify the factors influencing the oil compressibility and hereby the volumetric efficiency. The volumetric efficiency was measured and compared under varied oil compressibility conditions by varying elastic modulus, oil overflow pressure and oil volume. The results indicated that the measured volumetric efficiency agrees well with the calculated value. The compression and expansion of hydraulic oil have a dominant influence on the volumetric efficiency, resulting in a loss of 37% of volumetric efficiency as compared to 2.4%, 18% and 1%, respectively for losses associated with clearance volume, superheating of suction gas and pressure loss, for a diagram compressor under refueling conditions with suction pressure of 30 MPa and discharge pressure of 90 MPa. The volumetric efficiency reduced rapidly with the increased oil overflow pressure, at a rate of 5% decrease with every 10 MPa rise in oil overflow pressure. As the oil volume increased by 100% of the stroke volume, the volumetric efficiency droped by 5.5%. • A volumetric efficiency model with oil compressibility effects was established. • Oil compressibility had a major effect on the volumetric efficiency. • Major factors on oil influencing volumetric efficiency were quantitatively estimated. • Oil volume should be designed less than 3 times stroke volume.

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