Abstract

The microstructure of the Si phase in Al-20Si alloys solidified under high pressure was investigated. The results demonstrate that the morphology of Si phase transformed (bulk→short rod→long needle) with the increase of superheat temperature under high pressure. At a pressure of 3 GPa and a superheat temperature of 100 K, a microstructure with a uniform distribution of fine Si phases on the α-Al matrix was obtained in the Al-20Si alloy. In addition, a mathematical model was developed to analyze the spacing variation of the lamellar Al-Si eutectics under the effect of pressure. The lamellar Al-Si eutectics appeared at 2 GPa and superheat temperatures of 70–150 K, and at 3 GPa and superheat temperatures of 140–200 K. With the increase of pressure from 2 GPa to 3 GPa, the average spacing of lamellar Al-Si eutectics decreased from 1.2–1.6 μm to 0.9–1.1 μm. In binary alloys, the effect of pressure on the eutectic spacing is related to the volume change of the solute phase from liquid to solid. When the volume change of the solute phase from liquid to solid is negative, the lamellar eutectic spacing decreases with increasing pressure. When it is positive, the eutectic spacing increases with increasing pressure.

Highlights

  • The study of the influence of compression in the properties of metallic alloys, including morphology and microstructure, is extremely relevant for multiple technological applications [1,2,3]

  • The lamellar Al-Si eutectics appeared at 2 GPa and superheat temperatures of 70–150

  • A mathematical model was developed to analyze the trend of eutectic spacing of Al-Si alloy under the effect of pressure

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Summary

Introduction

The study of the influence of compression in the properties of metallic alloys, including morphology and microstructure, is extremely relevant for multiple technological applications [1,2,3]. Solidification phenomena are mainly described by nucleation [4,5,6], constitutional undercooling [7], interface stability [8,9,10,11,12,13], eutectic growth [14], dendritic growth [15,16], etc These theories mainly consider the effects of temperature and concentration but ignore that of pressure on the solidification process. The morphology and spacing of the eutectic can be affected by the GPa-level pressure. It is necessary to study the eutectic spacing of binary alloys under the effect of high pressure

Methods
Microstructures of lamellar
Morphological Evolution of the Si Phase
GPa and
Effect of Pressure on Eutectic Spacing
Conclusions
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