Effect of hierarchical multimodal microstructure evolution on tensile properties and fracture toughness of rapidly solidified Mg–Zn–Y–Al alloys with LPSO phase

Abstract

High fracture toughness Mg96.75Zn0.85Y2.05Al0.35 alloys featuring a multimodal microstructure were developed by rapidly solidified (RS) ribbon-consolidation processing. A non-heat-treated alloy that was prepared by consolidating the as-quenched ribbons exhibited a high tensile yield strength of ∼500 MPa, an elongation of ∼5%, and a plane-strain fracture toughness (KIc) of ∼9.5 MPa m1/2. Microstructure of the non-heat-treated alloy consists of two matrices: coarse-worked grains with a high kernel average misorientation (KAM) (group 1) and ultra-fine dynamically recrystallized (DRXed) grains with an intermediate KAM (group 2). The formation of ultra-fine DRXed grains with the precipitation of fine LPSO phase strengthens the alloy, but causes work-softening. The heat-treated alloy that was prepared by consolidating the RS ribbons heat-treated at 738 K exhibited a good balance of a high KIc (∼15 MPa m1/2), a reasonable yield strength (∼400 MPa), and a large elongation (∼12%) with a positive work-hardening rate. The optimized pre-consolidation heat-treatment produces multimodal microstructure having three matrices; a third group of the fine DRXed grains with a low KAM was formed in addition to groups 1 and 2. The formation of hierarchical multimodal structure in the grain size and KAM evokes strain-hardening, which has a positive effect on the fracture toughness.