Abstract

Extruded bulk nanostructured samples of Bi85Sb15 solid solution from particles with average sizes ∼ 2.105; 950; 650; 380; 30 and 15 nm were obtained and investigated their galvanomagnetic properties in the range of ∼ 77-300 K. Were investigated samples that have not passed heat treatment, and the same samples that have passed heat treatment. It was found that the electrical and thermal properties of Bi85Sb15 solid solution samples significantly depend on the size of nanoparticles and post-extrusion heat treatment. Heat treatment leads to a decrease in the concentration of current carriers and to an increase in the mobility of current carriers and the total thermal conductivity of the samples under study, which is mainly due to the electronic component of thermal conductivity. The change in thermal parameters is satisfactorily explained by changes in occurring in the structure of samples during extrusion and heat treatment and correlates well with changes in the electrical parameters of these processes.

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