Effect of heat treatment on microstructure evolution, strengthening mechanisms and mechanical properties of Zn modified Al–Mg alloys with Sc and Zr additions

Abstract

In this work, a new Al–Mg–Zn alloy was designed based on thermodynamic calculations combined with the concept of cooperative strengthening and toughening. The influence of different aging processes on microstructure and mechanical properties of the designed Al–Mg–Zn alloy was studied using experimental techniques including hardness testing, room-temperature tensile testing, EBSD, and HRTEM. The results indicate that after four different aging heat treatments, fine and uniformly distributed nano T-Mg32(Al, Zn)49 phases have precipitated within the grains. Compared to single-stage aging (140 °C/36 h, 180 °C/7 h), two-stage aging (90 °C/24 h + 140 °C/18 h, 90 °C/24 h + 180 °C/5 h) resulted in a smaller size and an increased number density of precipitated phases within the grains. After the aging process of 90 °C/24 h + 140 °C/18 h, the grains exhibited the smallest precipitated phases, being of 2.77 nm in size and a number density of 1.06 × 1023 #/m³. Additionally, TEM diffraction spot analysis identified the presence of Al3(Sc, Zr) precipitates within α-Al matrix. Under the aging process of 90 °C/24 h + 140 °C/18 h, the alloy exhibited superior mechanical properties with a tensile strength of 566 MPa, yield strength of 477 MPa, and elongation of 16.5%. The primary strengthening mechanisms of the presently investigated Al–Mg–Zn alloy include precipitation strengthening, solid solution strengthening, and grain boundary strengthening. A yield strength model considering various strengthening mechanisms is used to predict the yield strength based on thermodynamic calculations and experimental data. The research findings will offer theoretical insights guiding the design of compositions and heat treatment schedule for aluminum alloys.