Effect of H+ pre-irradiation on irradiation hardening and microstructure evolution of FeCoCrNiAl0.3 alloy with He2+ irradiation

Abstract

FeCoCrNiAlx-based high entropy alloys (HEAs) exhibit excellent high-temperature strength, good radiation tolerance and corrosion resistance. However, studies on light-ion irradiation damage are relatively lacking. The influence of hydrogen and helium effect on HEAs deserves further study, given their complex interaction during different sequence irradiation at different irradiation conditions. In the present study, FeCoCrNiAl0.3 HEA was irradiated under two different modes at 723 K, one is single He2+ and the other is pre-iradiation of H+ followed by He2+. Microstructure evolution and irradiation hardening were studied by transmission electron microscopy and nanoindentation technique. There is no distinct difference of the irradiation hardening rate between sequential H+-He2+ and single He2+ irradiated samples. A large number of irradiation-induced nano-defects were observed after pre-irradiation of H+, which act as sinks to trap the subsequent helium atoms in the H+-He2+ irradiated sample. Fine helium bubbles and dislocation loops with high density dispersed in both irradiated samples. Compared with single He2+ irradiation, pre-irradiation of H+ resulted in a decrease in bubble density and an increase in loop density in H+-He2+ irradiated sample, but had little effect on their size. It is speculated that the critical concentration of bubble formation originating from H-He-V clusters is supposed to be higher than that of HeV clusters at elevated temperatures in FeCoCrNiAl0.3 alloy, leading to the aggregation and redistribution of He atoms at the H-He-V clusters rather than the formation of stable bubble nucleus after succeeding He2+ irradiation. The influence of pre-irradiation of H+ on FeCoCrNiAl0.3 alloy on the formation of helium bubbles and the relationship between bubble, loop and irradiation hardening are discussed.