Effect of Graphene Quantum Dots (GQDs) on the mechanical, dynamic, and durability properties of concrete

Abstract

Addressing ecological concerns stemming from concrete usage is paramount, prompting exploration into additives for mitigation. Graphene quantum dots (GQDs) have been recognized for their potential to improve the mechanical attributes of cement composites. Additionally, the electrochemical reduction of a saturated solution of carbon dioxide (CO2) and monoethanolamine (CO2-MEA) effectively removes CO2 from the atmosphere. This study delves into the influence of GQDs on the mechanical and durability aspects of concrete. It is noted that the control mix of concrete without GQDs was specifically designed for concrete railway sleepers. Varied proportions of GQDs, ranging from 0.3 % to 1.2 % at 0.3 % increments, were incorporated to assess their impact on fresh and hardened concrete properties. Mechanical properties such as compressive strength, splitting tensile strength, flexural strength, and dynamic properties were evaluated. Durability assessments encompassing water absorption and chloride ion penetration were conducted. Microstructural analysis via Field Emission Scanning Electron Microscopy (FESEM) imaging and Energy-dispersive X-ray spectroscopy (EDS) elucidated the concrete's internal composition. Notably, an optimal GQDs percentage of 0.3 % was observed, signifying its efficacy in enhancing the performance of concrete. When 0.3 % of GQDs was added to concrete, compressive strength, split tensile strength, and flexural strength were enhanced by 10.8 %, 23 %, and 11 % respectively. The incorporation of GQDs resulted in a notable improvement in the fundamental frequencies and dynamic modulus of elasticity. Concurrently, a decrease in the damping ratio was observed for specimens containing GQDs. Additionally, the porosity and chloride penetration depth were lower by 6 % and 30 % for specimens with 0.3 % GQDs. The improvement in workability, mechanical, and dynamic properties of concrete, along with reducing CO2 from the atmosphere, makes GQDs an ideal eco-friendly material. This study is the first to open new pathways for the development of construction materials that are not only structurally superior but also environmentally responsible, marking a significant step forward in the field of civil engineering materials, especially in railway applications.