Abstract

Atomic force microscopy (AFM) was used to explore the effects of graphene modifier on the microstructure of asphalt. The morphologies of the before- and after-aged base asphalt and modified asphalt were performed and compared with analysis. The formation mechanism of asphaltic “bee structures” and the influence mechanism of graphene on asphalt were discussed from the classical theory of material science (phase transformation theory and diffusion theory). The results show that graphene facilitates the nucleation of “bee structures”, resulting in an increasing number and decreasing volume of “bee structures” in modified asphalt. Additionally, the anti-aging performance of the modified asphalt improved significantly because of graphene incorporation.

Highlights

  • Asphalt is a complicated mixture of various hydrocarbons and their nonmetallic derivatives

  • Cheraghian et al studied the ultraviolet aging resistance of fumed silica nanoparticles modified bitumen and the results show that the anti-ultraviolet aging property of modified asphalt is improved with the increase of nano silica content [18]

  • This reduction shows that the volume of the “bee structure” in asphalt decreased after modification by graphene

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Summary

Introduction

Asphalt is a complicated mixture of various hydrocarbons and their nonmetallic (oxygen, sulfur, and nitrogen) derivatives. Nanomaterials used as asphalt modifications have increasingly been studied to improve the mechanical and physical properties of bitumen. Some nanomaterials such as titanium dioxide (TiO2 ) [13], zinc oxide (ZnO) [14], graphene oxide (GO) [15], silicon dioxide (SiO2 ) [16], and montmorillonite [17] have been selected as modifiers to improve the road performance and extend the durability of asphalt. Shi et al investigated the properties and modification mechanism of GO-modified asphalt and discovered that a trace amount of GO restricted the movement of asphalt molecules and improved their high-temperature performance [23,24,25]. Phase transformation theory, and diffusion theory were introduced to interpret the mechanism of graphene on asphalt’s microscopic “bee structures.”

Experimental
Preparation of AFM Specimens
Effect of Graphene on Fundamental Properties of Asphalt
The “bee structure”
Effect of Graphene on Microstructure during Asphalt Aging
Height
Effect

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