Abstract

Cadmium sulfide quantum dots 1.3–5.6nm in size have been synthesized in sodium bis(2-ethylhexy1)sulfosuccinate (AOT)–water–isooctane micellar solutions with various [H2O]/[AOT] molar ratios (w=2.5, 5.0 or 10). Gamma irradiation method has been used to change the size and optical properties of quantum dots. It has been found that γ-irradiation reduces the size polydispersity of quantum dots in the micellar system and alters their fluorescent properties. Fluorescence intensity is enhanced after γ-irradiation. The average fluorescence lifetime of single quantum dots sized 5.2±0.4nm increases from 5.14 to 6.39ns after γ-irradiation at a dose of 7.9kGy. To the best of our knowledge, this is the first report on fluorescence lifetime of single CdS quantum dots in micellar solution.

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