Effect of gamma ray on self-induced diffraction patterns of organic compound Poly (methyl-methacrylate films

Abstract

Poly (methyl-methacrylate) (PMMA) doped organic compound (2-(2,3-dimethylphenyl-amino)-N-Phenyl benzamide) (2-NPb (films are produced on glass substrates with 5 μm thickness. The influence that gamma (γ) radiation has on the structure of the surface morphology of polymer films, the structure dependence of the optoelectronic properties and the optical properties of a prepared 2-NPb:PMMA film was studied under different doses (21, 42 and 64 KGy) of γ- rays emitted by a 137Cs source with an exposure rate of 0.56 Gy/min. The surface morphology of the 2-NPb:PMMA film for un-irradiated and irradiated sample was studied using a microscope with a digital camera along with texture, waviness and roughenss analysis of the entire surface of the films. The optical properties, together with an in-depth analysis of the dispersion energies and parameters, optoelectrical characteristics, and certain nonlinear optical parameters were comprehensively examined and addressed. In addition, the study of optical properties also included some nonlinear optical parameters. Results show that by doping organic compound (2-NPb) in PMMA, the absorption spectra of samples are decreased and superficial morphology of the film has been affected by γ-rays. As the polymer film was irradiated with a continuous-solid state laser (Solid-State-Laser −532–100 T) beam of 532 nm, self-diffraction ring patterns were seen, and it was shown that the diffraction ring patterns rely heavily on ring numbers and radiation dosage. The nonlinear refractive index,n2, for polymer film for un-irradiated and irradiated are estimated to be 0.23×10-6, 0.92×10-6, 1.64×10-6, 3.14×10-6cm2/W, respectively due to diffraction ring patterns. The diffraction ring patterns that were acquired via experimentation are then numerically estimated by making use of the Fresnel-Kirchhoff diffraction integral. The results of these calculations have satisfactory qualitative and quantitative accords.