Effect of gamma irradiation on the structural, mechanical and optical properties of polytetrafluoroethylene sheet

Abstract

In this study, the effects of gamma radiation on the chemical structure, mechanical and optical properties of polytetrafluoroethylene (PTFE) sheet were investigated with various doses up to 12kGy. The chemical changes in the structure were studied by FTIR spectroscopy. Also, effects of radiation on the different mechanical parameters such as Young's modulus, toughness, strain, and stress were studied at the maximum tolerable force and the fracture points. Furthermore, changing the various optical parameters such as absorption coefficient, Urbach energy, optical band gaps, refractive index, optical dispersion parameters and plasma resonance frequency were studied by UV–visible spectroscopy. Formation of a band at 1594cm−1, which was belonged to double carbon bonds, indicated that chain-scission was occurred at 12kGy gamma irradiation dose. As well, the mechanical results showed an increase in the elastic behavior of PTFE sheets and a decrease in the plastic behavior of it with absorbed dose increasing. Moreover, the results showed that gamma irradiation can effectively change the various optical properties of PTFE sheets due to different phenomena such as degradation of the main chains, occurring chain-scission, formation of free radicals and cross-linking in the polymer structure.