Abstract
A low-density clay ceramic syntactic foam (CSF) composite material was successfully synthesized from illitic clay added by fly ash cenospheres (CS) using the semi-dry formation method. The content of CS varied in the range of 10, 30, 50 and 60 vol %. Furthermore, reference samples without cenospheres were produced for property comparison. The materials comprising different amount of the additives were fired at temperatures of 600, 950, 1000, 1050, 1100, 1150 and 1200 °C. Firing times were kept constant at 30 min. Processing characteristics of the materials were evaluated in terms of density achieved and shrinkage observed as functions of both the CS content and the sintering temperature. The compressive strength and water uptake were determined as application-oriented properties. Except for the reference and the low CS level samples, the materials show an increase in strength with the increase in firing temperature, and a decrease of mechanical reliability with a decrease in density, which is typical for porous materials. Exceptions are the samples with no or low (10 vol %) content of cenospheres. In this case, the maximum strength is obtained at an intermediate sintering temperature of 1100 °C. At a low density (1.10 and 1.25 g/cm3), the highest levels of strength are obtained after sintering at 1200 °C. For nominal porosity levels of 50 and 60 vol %, 41 and 26 MPa peak stresses, respectively, are recorded under compressive load.
Highlights
In the modern world, one of the most challenging issues is energy efficiency over the full life cycle of a product
One specific approach with regards to this is the utilisation of fly ash cenosphere (FAC) addition into bulks to lighten building materials without substantially compromising strength, through the development of clay-ceramic syntactic foams
The present study was dedicated to the evaluation of clay matrix syntactic foams using cenosphere-type hollow spheres as filler to introduce porosity
Summary
One of the most challenging issues is energy efficiency over the full life cycle of a product. The increase of specific strength (MPa·kg−1 ·m3 ) and reuse of wastes can significantly contribute to solving these issues. One specific approach with regards to this is the utilisation of fly ash cenosphere (FAC) addition into bulks to lighten building materials without substantially compromising strength, through the development of clay-ceramic syntactic foams. The major advantage of cenospheres is their comparatively low cost, since the material is available as a by-product of coal-based energy generation. The mechanical properties of three-phase syntactic foams (SF) in terms of strength can theoretically exceed those of otherwise comparable two-phase foams thanks to the positive contribution of hollow filler particles’ shells, for example, towards mechanical performance [9,10]
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