Abstract

To evaluate the effects of extrusion process on the trans fatty acids (TFAs) formation in soybean crude oils, three different extrusion parameters, namely, extrusion temperature (80–160°C), feed moisture (10–26%), and screw speed (100–500 rpm), were carried out. It was found that only five different types of TFAs were detected out using gas chromatography-mass spectrometry. Before the extrusion started, the initial amount of total TFAs was 3.04 g/100 g. However, after extruding under every level of any variable, the total amounts of TFAs were significantly higher than those in the control sample (P < 0.05). For example, taking the effect of extrusion temperature into account, we can find that the highest amount of total of trans fatty acid (TTFA) was 1.62 times the amount of that in the control sample, whereas the lowest amount of TTFA was 1.54 times the amount of that in the control sample. Importantly, it was observed that the amounts of every type of trans fatty acid were not continuously increasing with the increase of the level of any extrusion variable. This phenomenon demonstrated that the formation and diversification were intricate during extruding process and need to be further studied.

Highlights

  • Trans fatty acids (TFAs) are geometrical isomers of unsaturated fatty acids containing nonconjugated carbon-carbon double bonds possessing the trans-configuration [1]

  • Dehulled full-fat soybean flakes were extruded for the extraction of soybean oil to study the effect of the extrusion process parameters, barrel temperature, feed moisture, and screw rotational speed, on the content of trans fatty acid (TFA)

  • By comparing the results shown above, we can conclude that extrusion technology could increase the formation of TFA

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Summary

Introduction

Trans fatty acids (TFAs) are geometrical isomers of unsaturated fatty acids containing nonconjugated carbon-carbon double bonds possessing the trans-configuration [1]. Previous studies have suggested that low level of TFAs in diet might derive from microbial biohydrogenation in the digestive tract of ruminant animals, whilst high level of TFAs is mainly produced through the consumption of partially hydrogenated edible oils in processed products [5, 6]. To increase oil yields, oil seeds are often subjected to pretreatments, such as flaking, cooking, extruding, and ultrasound, prior to the extraction process. Several studies have reported the influence of extrusion on the yield and the physicochemical properties of crude oils [9,10,11,12,13,14]. Wang and Johnson found that crude soybean oil from extruding process was low in phosphorus, FFA contents, and the oxidative stabilities [14]. According to Maga, the extent of hydrogenation and cis- to trans-isomerization of

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