Effect of excess Sr2+ on the microstructure and electrical properties of KSr2Nb5O15 ceramics

Abstract

KSr2Nb5O15 (KSN) ferroelectric ceramics were prepared by the solid-state reaction method using rod-like KSN particles as raw material. The effect of excess Sr2+ on the microstructure and electrical properties of KSN-xSr (x=0, 2, 4, 6, 8mol%) ceramics was investigated. The results indicated that all samples showed a single tetragonal tungsten bronze phase. Excessive Sr2+ diffuse into the A site of the KSN structure, compensating for the loss of A-site ions (Sr2+ and K+) of the raw materials, and alleviating the distortion of the lattice, which made the composition closer to the stoichiometric ratio of KSN. The Curie temperature shifted upward while the dielectric relaxor behavior was weakened as the excess Sr2+ content increased. In addition, dielectric tunability (Tu), ferroelectric, and piezoelectric properties of KSN ceramics were improved by increasing the excess Sr2+ content. The specimen with 6mol% excess Sr2+ showed the optimum electrical properties, with Tu=18.48% at E=1kV/mm, Pr=1.878µC/cm2, and d33=40 pC/N. This work confirmed that A-site vacancies in the KSN raw materials can be compensated for by excess Sr2+.