Abstract
Hydrosilylation of 1,5-hexadiene with chlorohydrosilanes catalyzed by homogeneous platinum catalyst to produce 5-hexenylchlorosilanes was studied. The presence of ether additives was highly effective in improving the regioselectivity and the yield. The formation of a double-bond rearrangement isomer, cis-, or trans-4-hexenylchlorosilanes, during the hydrosilylation was reduced drastically, as well.
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