Effect of electrochemical surface area on electroless copper deposition: Pd nanocubes as new activators

Abstract

In this study, the electrochemical surface area (ESA) and specific activity are used to obtain a fair comparison of various activators used for electroless copper deposition (ECD). Different sizes (i.e., 27, 48, and 63 nm) of Pd nanocubes (NCs) enclosed by {1 0 0} facets were successfully synthesized for use as new activators. The results of an analysis based on mixed potential theory indicated that the specific activities in terms of deposition current densities for the 27, 48, and 63 nm NCs and 9 nm nanoparticles (NPs) were 0.31, 1.06, 0.93, and 0.13 mA cm −2 ESA, respectively. From the results of electrochemical quartz crystal microbalance measurements, the specific activities calculated from the mean deposition rates of the 27, 48, and 63 nm NCs and 9 nm NPs were 29.62, 68.72, 54.77, and 9.72 μg cm −2 s −1, respectively. A specific activity order of 48 nm NC > 63 nm NC > 27 nm NC > 9 nm NP was obtained. The 48 nm Pd NCs exhibited the maximum activity towards the activation of the ECD bath.