Abstract
The Octahedral layer structure manganese oxides (Buserite and Birnessite) have been synthesized and modified by aging a MnOx gel which was produced from the redox reactions between Mn2+ and MnO4- in the presence of other metal cations (Mg2+, Ni2+, Co2+ or Cu2+). The present study investigates the structure transformation between Buserite and Birnessite using X-ray powder diffraction conducted on cation doped manganese oxides at different stages of before and after hydration. The results indicate that introduction of Mg2+ into the interlayer can completely achieve the structure transformation between Birnessite and Buserite after hydrated at 24h, and Ni2+ can partially reverse.
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