Abstract
Synthesis of biodegradable polycarbonates directly from carbon dioxide and diols has seen renewed interest. In the present report, the effect of a series of organic dihalides (CH2X2 and (CHX)2, where X = Cl, Br, and I) in the Cs2CO3-promoted copolymerization of 1 atm CO2 with diols has been studied. Structural analysis of the resultant polymers/oligomers by spectroscopic techniques reveals that a variety of main chain linkages can be obtained, depending on the dihalides used. Specifically, the methylene units from dibromomethane (DBM) are incorporated into the products as carbonate and ether linkages, and the methylene units from diiodomethane (DIM) are incorporated mainly as the ether linkage and without much CO2 incorporation. In comparison, all dihaloethanes examined lead to clean formation of alternating polycarbonates incorporating both the ethylene units from dihaloethanes and the diol units, and the halide is identified as the end group. The mechanistic pathways and the relative activity of the key intermediates are discussed in light of these results.
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