Effect of different initiators on the properties of diacetone acrylamide grafted starch-based adhesive

Abstract

Environmentally friendly and non-toxic bio-based adhesives are emerging as the most promising substitutes for petroleum-based adhesives, attracting increasing attention. This work involved the synthesis of a starch-based adhesive for particleboards by grafting diacetone acrylamide (DAAM) onto starch. The graft polymerization was initiated using three different initiators: ammonium persulfate (APS), hydrogen peroxide (H2O2)/ammonium ferrous sulfate system, and ceric ammonium nitrate (CAN). A comparative study was conducted to assess the varying effects of these initiators. The results showed that in the graft copolymerization of starch with DAAM, different initiators produced different types of free radicals, and CAN initiation produced alkyl radicals and long-chain alkyl radicals with a peak total spin value of 3.96 × 1015, and thus had the highest grafting efficiency and grafting rate of 72.59 % and 16.75 %, respectively. From the comparison of the total number of spins, it can be seen that CAN is more targeted for starch initiation. In addition, characterization results from Fourier transform infrared spectroscopy and confocal Raman spectroscopy showed that DAAM underwent a graft copolymerization reaction with starch. Notably, the adhesive initiated by CAN demonstrated the highest water resistance and mechanical strength, with an absorption thickness expansion and static bending strength of 8.52 % and 10.56 MPa, respectively.