Abstract

The effect of deep-level defects is a key issue for the applications of CdZnTe high-flux photon counting devices of X-ray irradiations. However, the major trap energy levels and their quantitive relationship with the device’s performance are not yet clearly understood. In this study, a 16-pixel CdZnTe X-ray photon counting detector with a non-uniform counting performance is investigated. The deep-level defect characteristics of each pixel region are analyzed by the current–voltage curves (I–V), infrared (IR) optical microscope photography, photoluminescence (PL) and thermally stimulated current (TSC) measurements, which indicate that the difference in counting performance is caused by the non-uniformly distributed deep-level defects in the CdZnTe crystals. Based on these results, we conclude that the CdZnTe detectors with a good photon counting performance should have a larger and Cd vacancy-related defect concentration and a lower A-center and Tei concentration. We consider the deep hole trap Tei, with the activation energy of 0.638–0.642 eV, to be the key deep-level trap affecting the photon counting performance. In addition, a theoretical model of the native defect reaction is proposed to understand the underlying relationships of resistivity, deep-level defect characteristics and photon counting performance.

Highlights

  • There is growing interest in the potential of direct converting semiconductor detectors for the detection of X-rays and γ-rays [1,2,3]

  • cadmium zinc telluride (CdZnTe) photon counting detectors, which can detect a photon flux in the order of a hundred million mm−2 s−1, are necessary for many applications such as medical and industrial imaging [8,9]. Such high-flux CdZnTe detectors have been reported [10], it is still a challenge to achieve large-scale commercial applications, primarily due to the material defects which can lead to the polarization effect [11,12,13,14,15,16]

  • The anode of the CdZnTe detector consists of pixels with an area of

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Summary

Introduction

There is growing interest in the potential of direct converting semiconductor detectors for the detection of X-rays and γ-rays [1,2,3]. The high-flux, multi-energy binning X-ray imaging CdZnTe detector technology, based on the pulse mode, has become a research hotspot [5,6,7] CdZnTe photon counting detectors, which can detect a photon flux in the order of a hundred million mm−2 s−1 , are necessary for many applications such as medical and industrial imaging [8,9] Such high-flux CdZnTe detectors have been reported [10], it is still a challenge to achieve large-scale commercial applications, primarily due to the material defects which can lead to the polarization effect [11,12,13,14,15,16]. The key deep-level trap that affects the photon counting performance will be assigned, which may provide ideas for the CdZnTe crystal growth technique for future photon counting applications

Experimental Section
X-ray Photon Counting Performance
Deep-Level Defect Characteristics
Conclusions
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