Effect of CuO as a dopant in TiO2 on ammonia and hydrogen sulphide sensing at room temperature

Abstract

The heterogeneous nanocomposites of CuO doped TiO2 nanoparticles were synthesized using sol gel method by varying the concentration of CuO as 0.1, 0.5 and 1mol% for the sensing of ammonia and hydrogen sulphide. The substitutional doping of CuO in TiO2 matrix was confirmed by the X-ray diffraction. Average crystallite size of the doped nanocomposites was found to reduce with increase in concentration of CuO. The 0.1mol% CuO doped TiO2 nanocomposites showed highest sensitivity to ammonia (97%) with response time of 2s, while 1mol% was selective to H2S gas (77%) with response time of 45s for 50ppm of each gas at room temperature.