Abstract

With the development of surface mount technology, solders are required for applications that require high reliability and dimensional stability. Composite solders, reinforced with particles in a conventional solder alloy, is an attractive and potential method. This study presents series results on the binary eutectic Sn-Bi composite solders reinforced with Cu <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">6</sub> Sn <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">5</sub> particles (0.5wt.% and 1wt.%). With this process, the wettability of composite solders was accepted although they were worse than that of Sn-58Bi. Compared with the spread area of Sn-58Bi, that of Sn-58Bi-1wt.% Cu <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">6</sub> Sn <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">5</sub> was reduced about 10% after reflowing for 30min. The reinforcement particles were well dispersed in the solder matrix and refined the grain size of β-Sn and Bi-rich phase. During the liquid interfacial reaction, the size of interfacial IMC was increased with reflowing time and it got larger for the addition of Cu <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">6</sub> Sn <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">5</sub> . The shear strength of composite solder joints was higher than that of Sn-58Bi/Cu. The fracture modes of composite solder were mainly ductile while that of Sn-58Bi/Cu was brittle when ε̇ =9×10 <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">-3</sup> s <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">-1</sup> .

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