Effect of Cr (III) on hydration, microstructure of magnesium phosphate cement, and leaching toxicity evaluation.

Abstract

The pollution caused by chromium and its compounds has caused severe harm to the environment, and waste stabilization/solidification containing these contaminants by magnesium phosphate cement (MPC) is one of the best ways to address this problem. If the mechanism between Cr3+ and MPC can be understood, it will significantly improve the latter's solidification performance with respect to ameliorating Cr pollution. In this paper, the compressive strength, microstructure, pH in the process of sample hydration, and leaching toxicity of solidified forms were studied by adding various amounts of Cr3+ into MPC. The setting time of MPC decreased at first and then increased as the Cr3+ concentration increased. The added Cr3+ reacted with the phosphate ions to form mineral phases, which changed the MPC matrix structure. The matrix's compressive strength was higher when the M/P ratio (MgO/KH2PO4 mass ratio) was smaller. When the concentration of Cr3+ was constant, and the M/P ratio was low (< 4:1), the matrix's compressive strength increased as the M/P ratio increased. The presence of Cr3+ changed the system's pH and affected the hydration products' morphology; this trend strengthened as the Cr3+ concentration increased. The highest leaching concentration of Cr3+ was 0.255mg/L, and the concentration decreased as the M/P ratio decreased. During solidification, the appropriate proportion of MPC can be selected according to the concentration of Cr3+ to achieve better solidification performance.