Abstract
Corrosion of steel reinforcement is a major factor affecting the durability and strength of reinforced concrete structures. This study investigated the influence of plant-derived corrosion inhibitors, applied as coatings, on the bond strength between reinforcing steel and concrete. Thirty-six 150 mm concrete cubes with 12 mm diameter embedded steel bars were prepared and divided into uncoated, corrosion inhibitor coated, and control groups. The samples were immersed in 5% sodium chloride solution over 360 days to accelerate corrosion. Pull-out testing measured the bond strength and failure load. The corroded samples showed 31-26% lower bond strength and 82-87% higher maximum slip than controls, indicating corrosion damage at the steel-concrete interface. However, inhibitor-coated samples displayed 24-36% higher bond strength and 42-43% lower maximum slip versus corroded samples. Although the coatings did not fully restore original bond strength, this demonstrates their effectiveness at protecting bond properties. Microscopic analysis revealed non-uniform, localized corrosion preferentially initiated at steel defects. Statistical correlations confirmed the direct relationship between steel weight loss and reductions in post-corrosion rebar weight due to material loss. While nominal rebar diameters showed minimal differences between sample types, localized diameter reductions and cross-sectional area increases in corroded samples highlighted discrete corrosion effects. These were mitigated in coated samples. Together with direct weight loss measurements, this proves corrosion occurred in unprotected samples. Overall, the significant recovery of bond strength, slip resistance, diameter, area, and weight in coated samples validates the success of the natural corrosion inhibitors in reducing steel deterioration and interface degradation. The results provide new insights on optimizing inhibitor coatings to maximize corrosion protection for reinforced concrete structures.
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