Effect of cooling rate on long-term recrystallized crystal of rice starch in the presence of flavor compounds

Abstract

This study evaluated the effect of cooling rate on starch recrystallization in the presence of 2,3-butanedione and 2-acetyl-1-pyrroline, which could form B-type and V-type complexes with starch, respectively. Rapid cooling resulted in poor perfection and high heterogeneity of both B-type and V-type recrystallized crystal. For B-type crystal, rapid cooling changed nucleation mode from instantaneous (Avrami index n < 1) to continuous mechanism (1 ≤ n ≤ 2), and decreased recrystallization rate from 0.0502 to 0.0160 d−n, indicating the increased retention of starch on 2,3-butanedione. V-type crystal was formed at initial stages of recrystallization, and inhibited the growth of B-type crystal. The loose crystalline obtained by rapid cooling is conducive to the retention of flavor compounds for B-type complexes (especially ≤14 days) and V-type complexes (especially ≤1 day). These results could provide guidance for maintaining fragrance of instant rice during long-term storage.