Abstract
Using a numerical implementation of polymer mean-field theory, we probe the effects of a structureless wall on the insertion free energies and the depletion interactions between nanoparticles in polymer solutions. Our results indicate that the insertion free energies and the polymer-induced interactions become mitigated in the presence of a wall. The range of influence of the walls is shown to correspond to the correlation length of the polymer solution. Surprisingly, our results demonstrate that even for particle sizes comparable to the correlation length of the polymer solution, the polymer depletion density profiles near the wall (in the absence of particles) can be used as a means to quantitatively predict the influence of the wall on both the insertion free energies and the depletion interactions.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
