Effect of Compound Surface Treatment on the Performance of Poly(butylene succinate)/Chemithermomechanical Pulp Fiber Composites

Abstract

ABSTRACTChemithermomechanical pulp fiber was pretreated by alkali solution to alter the surface characteristics of fibers. The untreated and treated fibers were used to prepare poly(butylene succinate)/chemithermomechanical pulp fiber composites with or without the incorporation of cellulose fatty acid ester (hydroxyethyl cellulose lauric acid ester). X-ray photoelectron spectrum analysis shows that the O/C ratio on the fiber surface increased after alkali treatment, indicating that part of lignin was removed during alkali treatment process. Scanning electron microcopy images indicate that the fiber surface was changed to rough after alkali treatment. The modification effect of hydroxyethyl cellulose lauric acid ester reflects as the improvement of fiber order in matrix, together with the enhancement of interfacial bonding, whereas, the modification effect of alkali treatment is mainly due to the enhancement of interfacial bonding. The integrated mechanical properties of composite prepared by alkali-treated fibers are superior to those of composite prepared by hydroxyethyl cellulose lauric acid ester-treated fibers. The combination of these two modification methods favors the enhancement of tensile and impact strengths of composite. However, in comparison with the composite prepared only by alkali treatment, the flexural strength and modulus would be despaired in a certain degree. When fibers were alkali treated, the shear viscosity of composite exhibited a larger increase, whereas the shear viscosity of composite prepared fibers with hydroxyethyl cellulose lauric acid ester treatment exhibits a slight decrease.