Abstract

In this paper we distinguish the contributions of switching, slide, creep and Debye relaxation modes of the domain wall dynamics to the low-frequency magnetic properties of chiral and racemic [MnII(HL-pn)(H2O)][MnIII(CN)6]·2H2O molecular ferrimagnets. We demonstrate that crystal and spin chirality affects the characteristic transition temperatures between different modes. In chiral crystals, transitions to the creep and Debye relaxation modes were observed at T = 7 K and 5 K, whereas in racemic crystals the same transitions occurred at higher temperatures T = 13 K and 9 K, respectively. Difference of the Peierls relief in chiral and racemic crystals is a possible reason of the chirality effect on the domain walls dynamics.

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