Effect of Cerium Content on Non–Metallic Inclusions and Solidification Microstructure in 55SiCr Spring Steel

Abstract

The effect of cerium content (0, 0.011, 0.017, 0.075 wt%) on non-metallic inclusions and solidification microstructures of 55SiCr high-strength spring steel was experimentally studied, along with thermodynamic calculations. The results show that Ce addition changes the type and size of inclusions in this steel and influences the characteristics of the solidification microstructure. In the sample without Ce addition, the main inclusions are MnS, SiO2, SiO2–MnS, and CaO–SiO2–MgO, and the equiaxed ratio in the solidification structure is 44.63%. However, when Ce content increases to 0.011 wt%, the inclusions in the steel become mainly Ce–S, Ce–O–S, and a small amount of MnS, and the equiaxed ratio increases to 50.42%. As the Ce content increases to 0.017 wt%, the inclusions are predominantly Ce–S, Ce–O–S, and Ce–O–S–Ca, while some Ce–P and Ce–O–P–C inclusions are also observed. The equiaxed ratio increases to 67.63%, showing the best effect on heterogeneous nucleation during solidification. When Ce content in the steel reaches 0.075 wt%, the Ce-containing inclusions are Ce–S, Ce–O, Ce–P, Ce–P–O, and Ce–O–S–As, and the size becomes larger. The formation mechanism of inclusions is explained by Gibbs free energy calculations and thermodynamic diagrams.