Effect of Cerium Content on Inclusions in an Ultra-Low-Carbon Aluminum-Killed Steel

Abstract

The effect of cerium on inclusions in an ultra-low-carbon Al-killed steel was studied at 1873 K (1600 °C) using laboratory experiments. The content of cerium in the steel varied from 0 to 0.028 wt pct. The contents of the total oxygen (T.O), total nitrogen (T.N), total sulfur (T.S), total cerium (T.Ce) and dissolved aluminum ([Al]) in the steel samples 1, 5, 10 and 30 minutes after adding cerium were measured, and inclusions were characterized using an automatic scanning electron microscope. It was found that a cerium-concentrated zone formed after the cerium alloy was added to the molten steel. Many inclusions were generated in the cerium-concentrated zone and then disappeared with the decrease of the cerium content. The variation of the inclusion composition was Al2O3 → CeAlO3 → Ce2O2S → Ce2O2S + CeS with the increasing cerium content in the steel, which agreed well with the thermodynamic analysis. The value of T.Ce/T.O was able to evaluate and predict the type of inclusions. A prediction model of the composition of inclusions was established based on thermodynamic calculation and mass balance and was validated by experimental data. When the value of T.Ce/(T.S + T.O) was ≥ 4.4, the average composition of inclusions changed little since most inclusions were fully modified.