Abstract
The effects of adding different Ce contents (0–0.32 wt.%) on the microstructure, mechanical properties, and fracture morphology of industrial A357 cast alloy in as-cast and T6 heat treatment were studied. The main purpose of this study is to improve the microstructure stability and tensile properties of industrial A357 cast alloy. The microstructural analyses indicate that the addition of Ce causes refinement of the α-Al primary phase for the reason that the formation of intermetallic compounds containing (AlSiCeMg) elements enriches the front of the solid–liquid interface, which causes an increase in constitutional undercooling. Simultaneously, the addition of Ce also affected the characteristics of eutectic Si particles, which make its morphology change from acicular structures into fragmented and spheroidized. This is mainly due to the formation of Ce-rich precipitates during solidification, which increase the constitutional undercooling and suppress the nucleation of the eutectic Si particles, resulting in the change of eutectic Si characteristics. Moreover, the needle-like morphology of a Fe-containing intermetallic is transformed into α(AlSiFeCe) phase containing rare earth Ce when part of the Ce atoms entered β(Al5FeSi) phase compounds. The tensile properties of the modified alloys were improved in the as-cast and T6 heat treatment as a consequence of simultaneous refinement of both secondary dendrite arm spacing and grains and the improvement of eutectic Si particles and Fe-containing intermetallic morphology. The fracture surface of the modified alloy has more dimples than the unmodified alloy, which indicates that the main fracture pattern of the modified alloy is dimple fracture caused by the crack of eutectic Si particles. The optimal percentage of Ce in industrial A357 cast alloy was determined to be 0.16 wt.% according to the change of microstructures structure and mechanical properties. These experimental results provide a new basis for adding rare earth Ce to improve the performance of parts in the actual production of industrial A357 cast alloy.
Highlights
The industrial A357 cast alloys has been progressively used to critical structural in aerospace and automobile industries for reasons of numerous advantages such as outstanding castability, corrosion resistance, etc. [1,2]
It is a known fact that the tensile properties of the Al-Si cast alloy are mainly influenced by the coarse dendritic structures, eutectic Si morphology, and intermetallic compounds [3,4]
The rare earth Ce is usually preferentially adsorbed in the twin concave groove of the Si phases; which is for the reason that the preferred orientation of eutectic Si along the Si growth the front of the solid–liquid interface after modification effect, due to the coefficient of diffusion of direction [35]
Summary
The industrial A357 cast alloys has been progressively used to critical structural in aerospace and automobile industries for reasons of numerous advantages such as outstanding castability, corrosion resistance, etc. [1,2]. Kang et al [16] found that the separate addition of Mg or Ce in Al-7Si-0.3Mg-0.2Fe alloy can cause grain and eutectic Si refinement, while the simultaneous addition of Mg and Ce has a more obvious grain refinement and excellent eutectic Si modification They suggest that the proper combination of Mg and Ce has a beneficial effect on grain size and eutectic Si morphology of Al-Si casting alloy production. The mechanism of rare earth Ce on the morphology of α-Al primary phase size and intermetallic compounds and eutectic Si modification of industrial A357 alloy was explained to clarify the effect of rare earth Ce on the mechanical properties of industrial A357 alloy
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