Effect of Cd doping on magnetocaloric effect and critical behavior analysis on perovskite Nd1−xCdxMnO3 (x = 0, 0.1, 0.2, 0.3, and 0.4) manganite polycrystals

Abstract

We report the doping effect of divalent cation Cd2+ at Nd-site of intermediate bandwidth manganite system NdMnO3 through the temperature- and magnetic field-dependent magnetization measurements. The parent compound shows paramagnetic-antiferromagnetic transition at 56 K, whereas Cd doped samples show the paramagnetic-ferromagnetic transition with fluctuating TC. During this transition, Nd1−xCdxMnO3 (x = 0.1 and 0.2) samples exhibit first order nature, whereas Nd1−xCdxMnO3 (x = 0.3 and 0.4) samples exhibit second order nature. It confirms a crossover from first order transition to second order transition while x = 0.2 to x = 0.3. By having first order transition, x = 0.2 sample exhibits high magnetic entropy change of 3.62 J kg−1 K−1 for the magnetic field change of 5 T out of all compositions. By having second order transitions, x = 0.4 sample exhibits a high relative cooling power of 319.71 J kg−1 for the magnetic field change of 5 T out of all the compositions. The critical behavior of second order transition of x = 0.3 and 0.4 samples has been analyzed using Arrott and Kouvel-Fisher plots. The estimated critical exponents of these samples are nearly matched with the mean free model, which can be explained by the existence of dipole-dipole interaction by the Cd doping which strengthens long range ferromagnetic interactions between the spins.