Abstract

Photoinduced hydrogen evolution with hydrogenase by use of a three component system consisting of triethanolamine, zinctetraphenylporphyrin tetrasulfonate (ZnTPPS 4) and methyl viologen was investigated in cationic surfactant, cetyltrimethylammonium bromide (CTAB). In the presence of CTAB, the lifetime of reduced methyl viologen and ZnTPPS 4 cation radical increased and effective hydrogen evolution from reduced methyl viologen with hydrogenase was accomplished.

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