Abstract

The thermal conductivity of GdSx solid solutions (Th3P4 structure) has been measured between 80 and 400 K. In all of the solid solutions studied, lattice thermal conductivity prevails. The high-temperature thermal conductivity of GdS1.500 is due not only to the phonon mechanism but also to radiative heat transport. At x < 1.49, filling of cation vacancies increases the electronic component, whose contribution rises with increasing Gd content.

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