Abstract

A semi-empirical model of carrier recombination accounting for hole localization by composition fluctuations in InGaN alloys is extended to polar and nonpolar quantum-well structures. The model provides quantitative agreement with available data on wavelength-dependent radiative and Auger recombination coefficients in polar LEDs. Comparison of calculated internal quantum efficiencies of polar and nonpolar LEDs enables an assessment of the roles of carrier localization, quantum-confined Stark effect, and native material properties for the efficiency decline in the “green gap”.

Highlights

  • Recent progress in growth and fabrication technology has enabled the demonstration ofInGaN-based light-emitting diodes (LEDs) with maximum external quantum efficiency (EQE) over~80% in the violet-blue spectral range [1,2]

  • In order to compare the theory with the experiment, the data on wavelength‐dependent radiative recombination coefficient (RRC) and Auger recombination coefficient (ARC) from [20] have been chosen as those providing the best correlation with independently estimated internal quantum efficiency (IQE) of state‐of‐the‐art LEDs

  • A semi-empirical model accounting for hole localization by InGaN composition fluctuations has been extended to quantum wells (QWs) of polar and nonpolar orientations

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Summary

Introduction

Recent progress in growth and fabrication technology has enabled the demonstration ofInGaN-based light-emitting diodes (LEDs) with maximum external quantum efficiency (EQE) over~80% in the violet-blue spectral range [1,2]. The maximum EQE values of LEDs operating in the green, ~40–50% [7,8], and yellow, ~20% [9], spectral ranges are remarkably lower than that in the violet/blue one, which cannot be attributed to insufficient light extraction from the LED dice [10]. A remarkable increase in the threshold current density and decrease in the wall-plug efficiency of InGaN-based laser diodes is observed in the same spectral range [11,12]. These “green gap” manifestations in both LEDs and laser diodes imply their common nature, pointing to some internal processes in the InGaN active regions

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