Abstract

The surface network structure of fly ash modified by calcium addition at high-temperature was analyzed by NMR, and K a method- (ICP-AES) rapid evaluation was used too. By activity exhibition of modified fly ash in cement paste, the effect of calcium addition course at high-temperature on fly ash's activity characteristics was studied. The results indicate: modified by calcium addition at high-temperature, fly ash's early K a value improvement, and ratio of activated Al 2 O 3 /SiO 2 was more than twice the average ratio of original fly ash, indicating the calcium addition course at high-temperature was not only destructive on Si-O bond, its destructive power on Al-O bond was also more apparent. Under the environment of cement paste, modified fly ash's reaction took place rapidly at early stage of cement hydration, and continually to consume Ca(OH) 2 produced by cement hydration.

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