Abstract

The effect of Ca doping in EuBaSrCu3O7−δ has been investigated by X-ray diffraction, ac susceptibility, and electrical resistivity measurements. X-Ray diffraction analyses of the samples showed that up to 30 at.% Ca can be substituted for Sr in EuBaSrCu3O7−δ, which has orthorhombic symmetry. The orthorhombicity decreases with increase inx, in EuBaSr1−xCax Cu3O7−δ, the material becoming tetragonal atx=0.2. Ac susceptibility and dc electrical resistivity measurements as function of temperature from 10 to 300 K showed that the superconducting transition temperatureTc decreases monotonically from 84 to 75K as the Ca concentrationx increases from 0.0 to 0.3 The decrease inTc can be attributed to the structural change taking place in EuBaSrCu3O7 as a consequence of replacement of Sr by Ca.

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