Abstract

Secondary compression studies can provide insights for evaluating the engineering potential and environmental impact of soil. The objective of this research was to investigate the effect of bound water content on the secondary compression of marine silty clay. To this end, a novel method was established based on thermogravimetric analysis (TGA) to determine the contents and limits of strongly bound water and weakly bound water for three typical marine silty clays including Tianjin mucky silty clay (TJ), Qingdao mucky silty clay (QD), and Weihai silty clay (WH). A total of 17 groups of uniaxial confined compression tests were performed for reconstituted samples at different absolute water contents under the condition of multistage loading to investigate their secondary compression characteristics. The results show that the initial dehydration temperature of strongly bound water (Ts) corresponds to the peak of the derivative thermogravimetry (DTG) curve. The values of Ts for TJ, QD and WH are 112.35 °C, 109.67 °C and 118.46 °C, respectively. The initial dehydration temperatures of weakly bound water (Tw) for TJ, QD and WH are 55.26 °C, 52.56 °C and 56.56 °C, respectively. The secondary compression coefficient Cα changes little before the strongly bound water limit and increases dramatically as weakly bound water content increases at the same vertical stress. A piecewise linear model and a quadratic polynomial model are established for calculating the average secondary compression coefficient from bound water content. Weakly bound water is the determining factor controlling secondary compression. Increasing the bound water content weakens the connection force and friction force among the particles and the viscosity of weakly bound water. The results will guide decisions on long-term settlement assessment and facilitate understanding of the secondary compression mechanism of marine silty clays affected by bound water.

Highlights

  • Clays have been widely used in environmental, engineering and agricultural fields as adsorption materials [1], liners for sanitary landfills [2], embankment dams, roadbeds [3,4], foundation materials, hydraulic barriers, and barrier layers for nuclear waste [5]

  • Naturally deposited marine silty clay mostly has a complex mineral composition and, has a heterogeneous surface and complex dehydration process without conspicuous steps in its TG curve. Considering this situation, an integrated approach incorporating TG and derivative thermogravimetry (DTG) curves was developed to identify and distinguish the different stages of the thermal reaction and distinguish between Strongly Bound Water (SBW) and Weakly Bound Water (WBW) by introducing a DTG curve, which has a higher resolution than the TG curve, rather than using the TG curve alone

  • This paper quantitatively investigates the effect of bound water content on the secondary compression of three typical marine silty clays using an integrated approach incorporating thermogravimetric analysis and uniaxial confined compression tests

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Summary

Introduction

Clays have been widely used in environmental, engineering and agricultural fields as adsorption materials [1], liners for sanitary landfills [2], embankment dams, roadbeds [3,4], foundation materials, hydraulic barriers, and barrier layers for nuclear waste [5]. With the rapid development of the economy and construction in coastal cities around the world, post-construction settlement assessment, underground space design [9] and reclamation projects [10,11,12] have become important topics in the areas of marine silty clays. In this context, a compression study on marine silty clays is critical for providing theoretical evidence for reclamation planning and environmental impact assessment. The secondary compression coefficient (Cα) is the most widely used parameter for describing and predicting secondary compression with conciseness and general applicability [13,14,16]

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