Abstract
AbstractSupramolecular polymerization of two regioisomeric naphthalene‐azobenzene dyads bearing barbituric acid and tri(dodecyloxy)phenyl units were studied in nonpolar solvent. Supramolecular polymers of the two compounds differ considerably in their topologies. While the isomer of which azobenzene unit was introduced along to its longer molecular axis formed randomly coiled supramolecular polymers with intrinsic curvature, the other of which azobenzene unit was introduced along to its shorter molecular axis formed linearly extended supramolecular polymers. Furthermore, due to their different degrees of geometrical changes accompanied with photoisomerization of the azobenzene unit, only the former showed a large topological change upon photo‐irradiation. The different structural and photoresponsive properties can be attributed to the distinct geometries of supermacrocyclic hydrogen‐bonded intermediates (rosettes).
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