Effect of AZO Substrates on Self‐Seeded Electrochemical Growth of Vertically Aligned ZnO Nanorod Arrays and Their Optical Properties

Abstract

We present a single step and an electrochemical synthesis of vertically aligned ZnO nanorod (NR) arrays, directly on transparent aluminium‐doped zinc oxide (AZO) electrodes. The NRs grow from mild, aqueous‐based solution at low temperature, with no need for catalysts or additional seed layer. The use of textured AZO as substrate allows for highly effective growth of hexagonally faceted, single‐crystalline ZnO NRs along the wurtzite c-axis. The matching of the crystal lattices initiates a self‐seeding route, thus the inherent growth habit of the AZO crystallites advances the vertical growth and alignment of NRs. Moreover, the thickness‐dependant grain size of the AZO layer provides a valuable feature for tuning the diameter of ZnO NRs grown atop. In the absence of any seed mediator, the interfacial quality is expected to improve significantly. This should enhance the thermal and electrical transport throughout the whole nanostructured transparent electrode. The NR growth was investigated under systematic manipulation of the synthesis variables in order to optimize growth conditions for highly aligned, single‐crystalline NRs with a large aspect ratio and a good optical quality. The structure and optical property of the AZO/ZnO NR ensembles were characterized by atomic force microscopy, scanning electron microscopy, X‐ray diffraction, photoluminescence, and ultraviolet‐visible transmission spectroscopy.