Effect of auxiliary acceptor on D-π-A based porphyrin sensitizers for dye sensitized solar cells

Abstract

Among the tetrapyrrolic class of compounds, porphyrin based sensitizers have attracted considerable attention due to their excellent performance in dye-sensitized solar cells (DSSCs). Herein, two new donor-[Formula: see text]-acceptor (D-[Formula: see text]-A) concept based porphyrin sensitizers having donor 3-ethynylphenothiazine tethered at meso- position, zinc porphyrin as [Formula: see text]-spacer and acceptor either 3-(4-(benzo[c][1,2,5]thiadiazol-4-yl)phenyl)-2-cyanoacrylic acid (LG22), and 3-(4-(benzo[c][1,2,5]thiadiazol-4-yl)thiophene-2-yl)-2-cyanoacrylicacid (LG23) were designed and synthesized. Both sensitizers were characterized by various spectroscopic techniques and electrochemical methods. Optical, electrochemical and optimized studies suggest that these dyes are suitable for sensitization of nanocrystalline TiO2. The optimized device studies showed the power conversion efficiencies (PCE) of 1.86% and 1.37% for LG22 and LG23 dyes, respectively using [Formula: see text]/[Formula: see text] liquid redox shuttle. Finally, Charge Extraction (CE), Intensity Modulated Photovoltage Spectroscopy (IMVS), Intensity Modulated Photocurrent Spectroscopy (IMPS) and Open Circuit Voltage Decay (OCVD) measurements were adopted to understand in detail the electron transfer properties at various interfaces in a way to understand the performance limiting processes in these novel porphyrin sensitizers.